第一部分 緒論(Part One Introduction) 一、物理化學(xué)實(shí)驗(yàn)的目的和要求 二、物理化學(xué)實(shí)驗(yàn)的安全知識(shí) 三、物理化學(xué)實(shí)驗(yàn)的設(shè)計(jì)思想 四、誤差理論和有效數(shù)字 五、實(shí)驗(yàn)數(shù)據(jù)的表示法和處理 1.Objective and requirement 2.Physical chemistry laboratory safety 3.Rules for designing of the physical chemistry experiment 4.Error theory and significant figures 5.Data reporting 第二部分 實(shí)驗(yàn)(Part Two Experjments) 實(shí)驗(yàn)一 燃燒熱的測定 Experiment 1 Heats Of Combustion 實(shí)驗(yàn)二 溶解熱的測定 Expenment 2 Heats of Solution 實(shí)驗(yàn)三 凝固點(diǎn)降低法測定摩爾質(zhì)量和滲透壓 Experiment 3 Molar Mass and Osmotic:Pressure by Freezing Point Depression 實(shí)驗(yàn)四 液體飽和蒸氣壓的測定 Expenment 4 Saturated Vapor Pressure of Pure LJquids 實(shí)驗(yàn)五 反應(yīng)平衡常數(shù)及分配系數(shù)的測定 Expenment 5 Equilibrium Constant 0f Reaction and PaItitiml Coefficient 實(shí)驗(yàn)六 完全互溶雙液系平衡相圖的繪制 Expenment 6 Phase Diagram of a Miscible Binary Liquid Svstem 實(shí)驗(yàn)七 雙組分簡單低共熔體系相圖的繪制 Expenment 7 Solid-liquid Binary Phase Diagram 實(shí)驗(yàn)八 三組分液-液系統(tǒng)相圖的繪制 Experiment 8 A Ternary Phase Diagram for a System of Three Liquids 實(shí)驗(yàn)九 電解質(zhì)水溶液電導(dǎo)的測定及應(yīng)用 Experiment 9 Measurement and Application of Electrolyte Solution Conductance 實(shí)驗(yàn)十 電動(dòng)勢法測溶液pH和反應(yīng)熱力學(xué)函數(shù) Experiment 10 Determinations of pH of Solution and Thermodynamic Functions by Electromotive Force Measurements 實(shí)驗(yàn)十一 一級反應(yīng)速率常數(shù)的測定 Experiment 11 Rate Constant for First Order Reaction 實(shí)驗(yàn)十二 碘化鉀與過氧化氫反應(yīng)的速率常數(shù)及活化能的測定 Experiment 12 Kinetics of Reaction between Potassium Iodide and Hydrogen Peroxide 實(shí)驗(yàn)十三 丙酮溴化反應(yīng)速率常數(shù)的測定 Experiment 13 Rate Constant and Activation Energy of the Bromination of Acetone 實(shí)驗(yàn)十四 乙酸乙酯皂化反應(yīng)速率常數(shù)及活化能的測定 Experiment 14 Rate Constant for the Saponification of Ethyl Acetate by Conductometric Method 實(shí)驗(yàn)十五 最大泡壓法測定溶液的表面張力 Experiment 15 Surface Tension of Solutions by Bubble Pressure Method 實(shí)驗(yàn)十六 固體在溶液中的吸附 Experiment 16 Adsorption of Solids in Solution 實(shí)驗(yàn)十七 乳狀液的制備和性質(zhì) Experiment 17 Preparation and Properties of Emulsion 實(shí)驗(yàn)十八 溶膠的制備及性質(zhì) Experiment 18 Preparation and Properties of Sols 實(shí)驗(yàn)十九 黏度法測定大分子的平均相對分子質(zhì)量 Experiment 19 Average Relative Molar Mass of the Macromolecule by Viscosity Method 實(shí)驗(yàn)二十 納米材料的合成與表征(綜合設(shè)計(jì)性試驗(yàn)) Experiment 20 Preparation and Characterization of Nanomaterials (Multi—designing Experiment) 實(shí)驗(yàn)二十一 藥物穩(wěn)定性及有效期測定(設(shè)計(jì)性實(shí)驗(yàn)) Experiment 21 Determination of Drug Stability and Shelf Life (Designing Experiment) 實(shí)驗(yàn)二十二 固體藥物常規(guī)理化常數(shù)的測定(綜合設(shè)計(jì)性實(shí)驗(yàn)) Experiment 22 Physical and Chemical Constants of Drugs (Multi—designing Experiment) 附錄(Appendices) 常用物理化學(xué)數(shù)據(jù)表(Reference Data of Experimental Physical Chemistry) 參考文獻(xiàn)(References)