有機化學(xué)實驗（英漢雙語版）

目錄
前言
Chapter 1 General Knowledge of Organic Chemistry Experiments 1
1.1 Rules for Organic Chemistry Laboratory 1
1.2 Safety Knowledge in the Organic Laboratory 2
1.3 Commonly Used Equipment and Apparatus of Organic Chemistry Experiments 6
1.4 Cleaning and Drying of Glassware 12
1.5 Heating，Cooling and Drying of Reagents in Organic Chemistry Experiments 13
1.6 Basic Requirements for Pre-lab Work，Lab Record and Lab Report 20
Chapter 2 Basic Operations of Organic Chemistry Experiments 25
Exp.1 Determination of Melting Point 25
Exp.2 Simple Distillation and Determination of Boiling Point 29
Exp.3 Recrystallization 32
Exp.4 Extraction 38
Exp.5 Vacuum Distillation 44
Exp.6 Steam Distillation 49
Exp.7 Fractional Distillation 54
Exp.8 Column Chromatography 57
Exp.9 Thin Layer Chromatography 60
Exp.10 Paper Chromatography 64
Chapter 3 Preparation Experiments of Organic Compounds 68
Exp.11 Preparation of Cyclohexene 68
Exp.12 Preparation of 1-Bromobutane 71
Exp.13 Preparation of Bromobenzene 75
Exp.14 Preparation of 2-Methyl-2-Butanol 77
Exp.15 Preparation of Diphenylmethanol 80
Exp.16 Preparation of 1，1'-Binaphthol (a Reference-based Experiment) 82
Exp.17 Preparation of Di-n-butyl Ether 83
Exp.18 Preparation of Cyclohexanone 86
Exp.19 Preparation of Benzalacetone and Dibenzalacetone 87
Exp.20 Preparation of Benzoin 90
Exp.21 Preparation of Benzoic Acid 92
Exp.22 Preparation of Adipic Acid 94
Exp.23 Preparation of Cinnamic Acid 97
Exp.24 Preparation of Coumarin-3-carboxylic Acid 99
Exp.25 Preparation of Furfuryl Alcohol and Furoic Acid 102
Exp.26 Preparation of Ethyl Acetate 104
Exp.27 Synthesis of Dibutyl Phthalate 107
Exp.28 Synthesis of Ethyl Acetoacetate 109
Exp.29 Preparation of Acetylsalicylic Acid (Aspirin) 110
Exp.30 Preparation of Acetanilide 112
Exp.31 Preparation of p-Acetamidobenzenesulfonyl Chloride 115
Exp.32 Preparation of p-Aminobenzenesulfonamide 118
Exp.33 Green Synthesis of N-bromosuccinimide 120
Exp.34 Synthesis of Methyl Orange 121
Exp.35 The Preparation and Beckmann Rearrangement of Benzophenone Oxime 124
Exp.36 Preparation of Aniline 126
Exp.37 Preparation and Resolution of Racemic α-Phenylethylamine 129
Exp.38 Optical Resolution of Trans-1，2-diaminocyclohexane 132
Exp.39 Preparation of 2，3； 5，6-Di-O-isopropylidene-α-D-mannofuranose 134
Exp.40 Isolation of Caffeine from Tea Leaves 136
Chapter 4 Reactivity Experiments of Organic Compounds 140
Exp.41 The Preparation and Reactivities of Ethylene and Ethyne 140
Exp.42 The Reactivities of Aromatic Compounds 143
Exp.43 The Reactivities of Some Alkyl Halides 145
Exp.44 The Reactivities of Alcohols and Phenols 148
Exp.45 The Reactivities of Aldehydes and Ketones 149
Exp.46 The Reactivities of Carboxylic Acids and Their Derivatives 151
Exp.47 The Reactivities of Amines 152
第1章 有機化學(xué)實驗的一般知識 155
1.1 有機化學(xué)實驗室規(guī)則 155
1.2 有機化學(xué)實驗室的安全知識 155
1.3 有機化學(xué)實驗常用儀器和裝置 158
1.4 玻璃儀器的洗滌和干燥 163
1.5 有機化學(xué)實驗中試劑的加熱、冷卻和干燥 165
1.6 實驗預(yù)習(xí)、實驗記錄和實驗報告的基本要求 169
第2章 有機化學(xué)實驗基本操作 174
實驗1 熔點測定 174
實驗2 簡單蒸餾及沸點測定 177
實驗3 重結(jié)晶 180
實驗4 萃取 184
實驗5 減壓蒸餾 188
實驗6 水蒸氣蒸餾 192
實驗7 分餾 196
實驗8 柱色譜 198
實驗9 薄層色譜 201
實驗10 紙色譜 204
第3章 有機化合物制備實驗 207
實驗11 環(huán)己烯的制備 207
實驗12 1-溴丁烷的制備 210
實驗13 溴苯的制備 212
實驗14 2-甲基-2-丁醇的制備 215
實驗15 二苯甲醇的制備 217
實驗16 1，1'-聯(lián)二萘酚的合成(文獻實驗) 218
實驗17 正丁醚的制備 219
實驗18 環(huán)己酮的制備 221
實驗19 芐叉丙酮和二芐叉丙酮的制備 222
實驗20 安息香的制備 224
實驗21 苯甲酸的制備 226
實驗22 己二酸的制備 228
實驗23 肉桂酸的制備 229
實驗24 香豆素-3-羧酸的制備 232
實驗25 呋喃甲醇和呋喃甲酸的制備 234
實驗26 乙酸乙酯的制備 236
實驗27 鄰苯二甲酸二丁酯的制備 238
實驗28 乙酰乙酸乙酯的制備 240
實驗29 乙酰水楊酸(阿司匹林)的制備 241
實驗30 乙酰苯胺的制備 242
實驗31 對乙酰氨基苯磺酰氯的制備 245
實驗32 對氨基苯磺酰胺的制備 247
實驗33 N-溴代丁二酰亞胺的綠色合成 248
實驗34 甲基橙的制備 250
實驗35 二苯甲酮肟的制備及貝克曼重排 252
實驗36 苯胺的制備 253
實驗37 外消旋α-苯乙胺的制備和拆分 255
實驗38 反-1，2-二氨基環(huán)己烷的手性拆分 258
實驗39 2，3；5，6-二-O-異丙叉基-α-D-呋喃甘露糖的制備 259
實驗40 從茶葉中提取咖啡因 261
第4章 有機化合物性質(zhì)實驗 264
實驗41 乙烯、乙炔的制備和性質(zhì) 264
實驗42 芳烴的性質(zhì) 266
實驗43 鹵代烴的性質(zhì) 268
實驗44 醇和酚的性質(zhì) 270
實驗45 醛和酮的性質(zhì) 271
實驗46 羧酸及其衍生物的性質(zhì) 272
實驗47 胺的性質(zhì) 273
參考文獻 276